Clean Water - Safe Harbor Project
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Clean Water - Safe Harbor Project

 

Some Papers and Information generally related to the Clean Water-Safe Harbor Project. Download these documents for your files.

1. “Turning a Liability into an Asset! The Story of an Old Power Plant” Abatement of lead paint (400,000 square feet) from a 1926 power plant located in environmentally sensitive area.

This coatings project involved removal by manually held ultra-high-pressure waterjetting (UHP WJ) of approximately 410,000 square feet of lead based paint from the historically significant Comal County Power Plant located in New Braunfels, Texas.

The owner is Lower Colorado River Authority, the coating manufacturer is Wasser High-Tech Coatings, the contractor is UHP Projects Inc.

The contractor can pop the lid on the can; stir it up; and put it into suspension.

The surfaces varied from old steel with multi-layered paint, to hard brick, to horse hair filled mortar and very soft, old brick.

All three participants, the owner, the coatings supplier and the contractor approached this project with a "win-win" attitude.

2. This limited study is not intended to provide a complete evaluation of the use of porous adsorbents for the removal of dissolved heavy metals from storm water, but to determine if commercially available products could be adapted for this task. As defined in the project proposal, the objectives of the project were to (1) evaluate the potential use of a number of adsorbents for the removal of heavy metals from storm water, and (2) determine the feasibility of placing a porous adsorbent within a storm water system as a BMP. 1997, 20 pages, 0.5 Mb

Even with the most sophisticated and rigorous best management practices (BMPs), some heavy metals are invariably transported into storm water collection systems.

The engineering literature provides no details on the specific configurations of storm water collection systems typically encountered at a large commercial or Naval shipyard, however, a mix of combined sewers, sanitary sewers and separate storm water sewers would be expected.

The final sections of this report focus on the evaluation and testing of adsorbent materials for the removal of heavy metals from a synthetic saline storm water.

For the sorption of metals to the carbonaceous adsorbents we tested, physical entrapment of the metal into internal pores was probably the dominant sorption mechanism (i.e., physisorption).

3. “WASTE WATER TREATMENT TECHNOLOGY SURVEY” The objective of this project was to investigate methods for treating the ballast water from naval vessels that have compensated fuel tanks., 1998, 50 pages, 1.5 Mb

The objective of this project was to investigate methods for treating the ballast water from naval vessels that have compensated fuel tanks.

With an oil and water interface, there is some mixing of fuel and water so that free oil and emulsified oil are part of the ballast water.

However, most shipyards that occasionally deal with compensated-fuel-tank ships are also faced with numerous other waste water processing needs and opportunities, both within the yard and in the surrounding port areas.

The basic approach to the economic analysis was to identify the capable systems and perform a cost / benefit analysis on some of the most promising types.

4. “Document Technologies Available to Clean Brackish Water to 50 PPT TBT Levels”The purpose of this study is to identify practical technology that can be used by shipyards to remove tributyltin (TBT) from large volumes of water to levels below 50 parts per trillion. 1997, 63 pages, 1.1 Mb

T he purpose of this study is to identify practical technology that can be used by shipyards to remove tributyltin (TBT) from large volumes of water to levels below 50 parts per trillion.

Procedures for treating wastewater at the Livermore facility start with the addition of iron (II) chloride to remove sulfides and to promote settling.

In one sewage plant in Switzerland, TBT levels in water were reduced from 181 ppt to 9 ppt mainly by sedimentation in the primary classifier and subsequent treatment steps (Fent 1996).

Residual concent rat ions of mo n obut y lt in at t h e ug/L lev el in t h e effluen t will p ro bably n o t p o se a h azard t o aquat ic o rgan isms since t he effluent will event ually be great ly dilut ed and t oxicit y of monobut ylt in t o aquat ic organisms has only been observed at much higher concentrations (mg/L).

5.Air and Wastewater Quality Control

The objective of this project was to perform a survey of U.S. shipyards and similar industries to determine what technologies are currently being implemented or planned to prevent or reduce air emissions and wastewater discharges from facility operations.

There are numerous reports available, summarizing and comparing various "clean technologies", which have potential application in the shipyard environment.

Biological treatment capabilities include activated sludge, nitrification and denitrification, anaerobic and aerobic digestion, and wetlands.

Internet Address: http://terrassa.pnl.gov:2080 Pacific Northwest National Laboratory works in all phases of the technology development cycle from Research and Development to industrial implementation.

They are studying carbon dioxide (CO2) pellet blasting, FLASHJETTM coating removal, laser paint stripping, plastic media blasting, sodium bicarbonate wet stripping, water blasting and wheat starch blasting.


6. Treatment of Zinc and Copper in Wastewater

Coagulation studies have concentrated on evaluating the performance of two metal-salt coagulants and their ability to remove copper and zinc with the large amount of the particulate material that is typically present in shipyard wash waters.

The primary variables that control particulate material removal, and also the adsorption of adsorption-amenable organic compounds, are coagulation, pH and coagulant dose.

Sample 1 was removed after the sample had passed through the sand filter, and Samples 2 and 3 were taken after the sample had passed through the respective activated carbon columns.

The purpose of the sand filter was to determine if additional removal of fine particulates from the sample could significantly reduce the copper and zinc levels.

7. Review Paper on Organotin

Michael A. Champ, "Advanced Technology Research Project (ATRP) Corporation, PO Box 2439, falls Church, VA 22042-3934, Tel: 1-703-237-0505; fax: 1-703-241-1278, e-mail: machamp@aol.com

Copyright (C) 2000 Elsevier Science B.V. All rights reserved. Used by permission of the Author.

Abstract Achieving consensus on equitable and effective national and global regulation s for the use of organotins as biocides in antifouling boat bottom paints has proven to be very complex and difficult for a variety of reasons as discussed in this paper. There appears to be broad agreement among stakeholders about the effectiveness of tributyltin (TBT) in antifouling paints. A draft Assembly Resolution prepared by the Marine Environmental Protection Committee (MEPC) of the International Maritime Organization (IMO) to propose a global ban on the use of organotins in antifouling paints was approved by the IMO at its 21st regular session (November 1999). In approving the Resolution, the Assembly agreed that a legally binding instrument (global convention - an international treaty) be developed by the Marine Environmental Protection Committee that should ensure by 1 January 2003, a ban on the application of tributyltin (TBT) based antifouling paints; and 1 January 2008 as the last date for having TBT-based antifouling paint on a vessel. The Assembly also agreed that a diplomatic conference be held in 2001 to consider adoption of the international legal instrument. Monitoring, policing, enforcement, fines and record-keeping are yet to be defined. In addition, the MEPC has also proposed that IMO promotes the use of environmentally-safe anti-fouling technologies to replace TBT. Existing national regulations in the US and Europe have: (1) restricted the use of TBT in antifouling boat bottom paints by vessel size (less than 25 m) in length, thus eliminating TBT from the smaller and recreational vessels that exist in shallow coastal waters where the impacted oysters species grow; (2) restricted the release rates of TBT from co-polymer paints; and (3) eliminated the use of free TBT in paints. The present movement toward a global ban suggests that the above regulatory approach has not been sufficient in some countries. Advocates of the ban cite international findings of: (1) higher levels of TBT in surface waters of ports and open waters; (2) imposex still occurring and affecting a larger number of snail species; (3) TBT bioaccumulation in selected fisheries; and (4) the availability of 'comparable' alternatives to TBT with less environmental impact. The global ban has been absent of a policy debate on the: (1) lack of 'acceptable and approved' alternatives in many nations; (2) appreciation of market forces in nations without TBT regulations; (3) full consideration of the economic benefits from the use of TBT; (4) 'acceptance' of environmental impacts in marinas, ports and harbors; and (5) realization of the 'real' time period required by ships for antifoulant protection (is 5-7 years necessary or desirable?). Estimates of fuel savings range from $500 million to one billion. In assessing the environmental impact from TBT, there are two sources: the shipyard painting vessels and the painted vessel itself. Today vessels can be painted with regulated or banned antifouling materials by boatyards in a country that does not have TBT regulations and subsequently travel in international and regulated national waters and thus bringing the impact back to the country which was trying to prevent it. Worse, local and national regulations for TBT have proven to be the antithesis of the popular environmental cliché -- 'Think Globally and Act Locally.' Legislative policies enacted by 'regulated' countries to regulate the use of TBT to protect their local marine resources have subsequently had far reaching environmental and economic impacts which have in essence transferred TBT contamination to those countries least able to deal with it. Market forces are selective for cheap labor and cheap environments. 'Unregulated' countries have unknowingly accepted the environmental and human health risks to gain the economic benefits from painting TBT on ships. Unfortunately, these countries may not have the funding or environmental expertise available for the monitoring, research and technology development essential to use these modern high technology compounds. Therefore, they end up with more contamination because they do not have the necessary regulatory structure to prevent it. In the US coastal zone, federal and state regulations have had a significant impact on reducing TBT levels, generally to well below the provisional water quality standard of 10 ng / l, and in bivalve tissues. Current environmental and marine and estuarine water concentrations are well below predicted acute TBT toxicity levels. Estimation of chronic toxicity effects using mean water TBT concentrations indicate that current levels would be protective of 95% of species. Analysis of allowable daily intake r oral reference dose values from market basket surveys and the NOAA National Status and Trends data suggest that there is no significant human health risk from consuming seafood contaminated with TBT. Most of the data that exceeded these values were from areas of high TBT input from ports, harbors and marinas (commercial shipping, shipyards and drydock facilities) and sites of previous contamination. In the US, at this time, TBT environmental data and lack of acceptable alternatives does not justify a global ban for TBT. Three significant aspects of the regulatory discussion should not be forgotten: (1) none of the available alternatives to TBT-based antifouling paints has been approved on a global basis or in the US by the USEPA, the VOC levels are above current regulatory levels and in the past such reviews have taken up to 54 months to complete; (2) studies in Ireland have found that the use of TBT has greatly reduced the threat and risk of introduction of invasive exotic marine species in foreign waters; and (3) a biofouled ship can transport on its bottom approximately 2 000 000 marine organisms which is significant when compared to the small numbers transported in ballast waters. Alternatives to TBT are available, but not proven and accepted on a global basis. Unfortunately in the less than 1000 days remaining before the proposed IMO ban, an international independent process is not available to expedite the IMO recommendation to evaluate and select alternatives to TBT. The cost to shipowners for this failure has been estimated to range from $500 million]$1 billion annually. A third party, neutral, independent, international Marine Coatings Board has been proposed to supplement the national regulatory process by providing the international standardized scientific data and information of the highest quality. The cost of the Marine Coating Board to evaluate available alternatives has been estimated to be $10 million / year or 1-2% of the estimated annual direct costs to shipowners of not having comparable antifouling marine coating alternatives to TBT. In ship operating coasts, this is less than $1 / day per vessel in global commerce with a total ROI in the first 37 days of 2008.

 

8. Environmental and Economic Consequences of the Convention to Ban Certain Antifoulants.

The ban on TBT has come about because of TBT has detrimental effects on nontargent marine organisms.

Serious concern has been expressed by a wide variety of experts for the need to identify in the Treaty the necessary regulatory language for: the "safe" removal, treatment, and disposal of marine antifoulants deemed "harmful" by the Treaty and (2) who is liable for the future dredging and disposal of TBT-contaminated port and harbor sediments - to also protect the marine environment.

Founded and currently the Editor-in-Chief of the international peer review journal: Spill Science & Technology Bulletin published by Elsevier Science in Oxford, England, published quarterly.

Edited 10 Published Conference Proceedings from National Conferences such as IEEE and Marine Technology Society Conference Special Volumes (1982-2001).